Making silicone masks

I've been making my own latex masks for a couple of years now, and am wanting to branch into experimenting with silicone. I've got lots of questions. First, what material is best to use when making the mold? From there, what is the best way to make the mold? Is there a type of silicone that is best for something like this? What about casting techniques? If there are articles or videos/DVDs that would cover this well, I'm open to suggestions. Thanks!
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